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It depends on the poison. If we use the colloquial term of the word and include toxins and poisons, then many things, like proteins, will undoubtedly be denatured or degraded and eventually become harmless. For example, tetrodotoxin, ricin, botulinum, etc. I hope this poison has the shortest shelf life, because they are relatively.
An organic poison will lose its toxicity all together in few years but there are a few inorganic poisons that become more toxic but are slow. So let's deal with organic poisons first! Many organic poisons like herbicides and insecticides break down over time, this means that after they expire they will have to be used in a larger amount to be lethal. If your poison is a chemical with an inert oxide or hydrated form, it would become less poisonous as it slowly reacts with the atmosphere. On the other hand, if it's a biological poison (is that a thing?), it might get stronger and then weaker as the colony grows and then dies. Not a poison expert in the slightest but that's my two cents. As anything can be a poison depending on dose, if we look at medical active ingredients, the degradation products of many might be less toxic, but also less effective. Does rat poison lose effectiveness over time? Rat poison does expire and degrade because it is typically made from organic materials with a shelf life.
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